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Introduction; Electrostatics; Electrical Measurements; Current Electricity; Electromagnetism; Conduction in Liquids and Gases; Sources of Electromotive Force; Alternating Currents; History
Electricity, all the phenomena that result from the interaction of electrical charges. Electric and magnetic effects are caused by the relative positions and movements of charged particles of matter. When a charge is stationary (static), it produces electrostatic forces on charged objects, and when it is in motion it produces additional magnetic effects. So far as electrical effects are concerned, objects can be electrically neutral, positively charged, or negatively charged. Positively charged particles, such as the protons that are found in the nucleus of atoms, repel one another. Negatively charged particles, such as the electrons that are found in the outer parts of atoms, also repel one another (see Atom). Negative and positive particles, however, attract each other. This behaviour may be summed up as: like charges repel, and unlike charges attract.
The electric charge on a body is measured in coulombs (see Electrical Units; International System of Units). The force between particles bearing charges q1 and q2 can be calculated by Coulomb’s law,
Every electrically charged particle is surrounded by a field of force. This field may be represented by lines of force showing the direction of the electrical forces that would be experienced by an imaginary positive test charge within the field. To move a charged particle from one point in the field to another requires that work be done or, equivalently, that energy be transferred to the particle. The amount of energy needed for a particle bearing a unit charge is known as the potential difference between these two points. The potential difference is usually measured in volts (symbol V). The Earth, a large conductor that may be assumed to be substantially uniform electrically, is commonly used as the zero reference level for potential energy. Thus the potential of a positively charged body is said to be a certain number of volts above the potential of the Earth, and the potential of a negatively charged body is said to be a certain number of volts below it.
The first artificial electrical phenomenon to be observed was the property displayed by certain resinous substances such as amber, which become negatively charged when rubbed with a piece of fur or woollen cloth and then attract small objects. Such a body has an excess of electrons. A glass rod rubbed with silk has a similar power; however, the glass has a positive charge, owing to a deficiency of electrons. The charged amber and glass even attract uncharged bodies (see Electric Charges below). Protons lie at the heart of the atom and are effectively fixed in position in solids. When charge moves in a solid, it is carried by the negatively charged electrons. Electrons are easily liberated in some materials, which are known as conductors. Metals, particularly copper and silver, are good conductors. see Conductor, Electrical. Materials in which the electrons are tightly bound to the atoms are known as insulators, non-conductors, or dielectrics. Glass, rubber, and dry wood are examples of these materials. A third kind of material is called a semiconductor, because it generally has a higher resistance to the flow of current than a conductor such as copper, but a lower resistance than an insulator such as glass. In one kind of semiconductor, most of the current is carried by electrons, and the semiconductor is called n-type. In an n-type semiconductor, a relatively small number of electrons can be freed from their atoms in such a manner as to leave a “hole” where each electron had been. The hole, representing the absence of a negative electron, is a positively charged ion (incomplete atom). An electric field will cause the negative electrons to flow through the material while the positive holes remain fixed. In a second type of semiconductor, the holes move, while electrons hardly move at all. When most of the current is carried by the positive holes, the semiconductor is said to be p-type. If a material were a perfect conductor, a charge would pass through it without resistance, while a perfect insulator would allow no charge to be forced through it. No substance of either type is known to exist at room temperature. The best conductors at room temperature offer a low (but non-zero) resistance to the flow of current. The best insulators offer a high (but not infinite) resistance at room temperature. Most metals, however, lose all their resistance at temperatures near absolute zero; this phenomenon is called superconductivity.
One quantitative tool used to demonstrate the presence of electric charges is the electroscope. This device also indicates whether the charge is negative or positive and detects the presence of radiation. The device, in the form first used by the British physicist and chemist Michael Faraday, is shown in Figure 1. The electroscope consists of two leaves of thin metal foil (a,a_) suspended from a metal support (b) inside a glass or other non-conducting container (c). A knob (d) collects the electric charges, either positive or negative, and these are conducted along the metal support and travel to both leaves. The like charges repel one another and the leaves fly apart, the distance between them depending roughly on the quantity of charge. Three methods may be used to charge an object electrically: (1) by contact with another object of a different material (for example, touching amber to fur), followed by separation; (2) by contact with another charged body; and (3) by induction. Electrical induction is shown in Figure 2. A negatively charged body, A, is placed between a neutral conductor, B, and a neutral non-conductor, C. The free electrons in the conductor are repelled to the side of the conductor away from A, leaving a net positive charge at the nearer side. The entire body B is attracted towards A, because the attraction of the unlike charges that are close together is greater than the repulsion of the like charges that are farther apart. As stated above, the forces between electrical charges vary inversely according to the square of the distance between the charges. In the non-conductor, C, the electrons are not free to move, but the atoms or molecules of the non-conductor are stretched and reoriented so that their constituent electrons are as far as possible from A; the non-conductor is therefore also attracted to A, but to a lesser extent than the conductor. The movement of electrons in the conductor B of Figure 2 and the reconfiguration of the atoms of the non-conductor C give these bodies positive charges on the sides nearest A and negative charges on the sides away from A. Charges produced in this manner are called induced charges and the process of producing them is called induction.
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